A BRIEF HISTORY OF ATOMIC STRUCTURE
|
450 B.C.
|
DEMOCRITUS,
a Greek philosopher, proposed that all matter is made up of particles called
atoms, meaning indivisible. |
1678
|
CHRISTIAN
HUYGENS, postulated that light is a wave which
moves and acts like waves in water. |
1684
|
SIR
ISAAC NEWTON stated that "matter is formed
of solid, massy impenetrable particles", of some definite size which
combine in various ways to produce substance. |
1687
|
SIR
ISAAC NEWTON developed the "corpuscular theory
of light." Light is thought to be the result of "luminous corpuscles"
or particles which produce the waves we see as light. |
1864
|
CLERK
MAXWELL developed a series of equations expressing
the relationship between electric and magnetic forces. |
1873
|
CLERK
MAXWELL stated "we have strong reason to conclude
that light itself is an electromagnetic disturbance." |
1887
|
HEINRICH
HERTZ discovered the photoelectric effect. If a
beam of light falls on a clean metal plate in a vacuum, the plate becomes
positively charged. |
1895
|
SIR
JOSEPH THOMPSON proved the existence of a negatively
charged particle, termed the electron, which existed as part of the atom. |
1900
|
MAX
PLANCK developed the basis of modern Quantum Theory
by finding that light is emitted or absorbed by an atom in discrete amounts
called quanta. |
1905
|
ALBERT
EINSTEIN in his explanation of the photoelectric
effect proposed that light must have both the properties of particles as
well as those of waves. |
1911
|
LORD
ERNEST RUTHERFORD discovered that the atom's nucleus
is very small in relation to the entire atom. He proposed that the negatively
charged electrons were revolving around a heavier, charged nucleus. |
1913
|
NIELS
BOHR synthesized Rutherford's discovery into a
reasonable model of an actual atom, using hydrogen as his example. Bohr
proposed a positively charged central nucleus with electrons moving about
it in circular orbits. The important feature in Bohr's theory was that electron
orbits could occur only in specific, predetermined paths. If an electron
absorbs energy, it is moved to an orbit further from the nucleus. Conversely,
when it drops to an orbit nearer the nucleus, it gives off energy in the
form of light. Different colors of light are produced depending on which
orbit the electron starts from and to which orbit it drops. |
1916
|
ARNOLD
SOMMERFELD proposed elliptical orbits in addition
to Bohr's circular ones. Sommerfeld's ellipses altered Bohr's model by showing
electrons moving inwardly and outwardly without radiating or absorbing energy. |
1923
|
LOUIS
DE BROGLIE proposed that all objects have properties
of waves. The lighter the object, the more pronounced the wave effect. An
object as small as the electron would act very much like a wave, forming
stationary waves around the nucleus. |
1925
|
WOLFGANG
PAULI developed the Pauli Exclusion Principle which
states that no two electrons within the same atom can have the same set
of quantum numbers. |
1925
|
UHLENBECK
& GOUDSMIT showed that the electron possesses
a spin in either direction upon its axis. |
1926
|
ERWIN
SCHROEDINGER developed an equation, based on de
Broglie's wave idea, expressing the probable location of an electron. These
probable regions of occupancy were conceived as clouds of charge around
the nucleus. Different shapes occurred for different types of orbitals. |
1927
|
WERNER
HEISENBERG derived his "Uncertainty Principle"
which states that it is impossible to determine simultaneously the momentum
and position of an electron. |
1929
|
LINUS
PAULING showed how 2 electrons could form a more
stable wave arrangement if their spins were antiparallel. |
CURRENTLY ACCEPTED SCIENTIFIC
DESCRIPTION OF AN ATOM
|
1.
|
At the
center of the atom is a small, dense positively charged nucleus consisting
primarily of protons and neutrons. |
2.
|
Moving
around the nucleus are negatively charged electrons which account for only
1/5000 of the atom's mass -- the rest of the mass being in the nucleus.
Most of the atom is empty space. The motion of the electrons is not described. |
3.
|
The electrons
in an atom are allowed to have only certain energies. The allowed states
are described by a set of "quantum numbers", which indicate their
average distance from the nucleus, their angular momentum and its direction,
and the electrons' spin direction. |
4.
|
Light
of a specific color is emitted or absorbed when electrons change from one
state to another. |
5.
|
The "Heisenberg
Uncertainty Principle" states that the position and momentum of an
electron cannot be simultaneously determined. The interpretation of the
Heisenberg principle is that the atom's structure and the interactions of
its electrons are random and can be discussed only statistically. |
6.
|
Even though
the electron's exact position cannot be determined, if its energy is known,
the theory predicts the probability that an electron could be at a particular
place. |
7.
|
If the
probability location of an electron of known energy is plotted in space,
the plot looks like a fuzzy cloud of varying density, the shape varying
with differences in angular momentum. It always has a definite symmetry
about the nucleus. Some of the clouds or orbitals are spherical, others
are like dumbbells, while others are more complex. |
8.
|
In describing
an atom with many electrons, the charge clouds of one shell are superimposed
in space with those of other shells. |
Sections: 1
2
3
4
5
6
7
8
|